To slightly extend Robert's example - even if you don't have an instance of the discriminated union, you can use F# reflection to get the information about the type (such as types of the arguments of individual cases). The following extends Robert's sample ans it also prints the types of arguments:
open Microsoft.FSharp.Reflection
let ty = typeof<option<int>>
let cases = FSharpType.GetUnionCases ty
printfn "type %s =" ty.FullName
for case in cases do
printf "| %s" case.Name
let fields = case.GetFields()
if fields.Length > 0 then
printf " of"
for fld in fields do
printf " %s " fld.PropertyType.FullName
printfn ""
For example, for option<int>
type, you'll get (I slightly simplified the output):
type Microsoft.FSharp.Core.FSharpOption`1[System.Int32] =
| None
| Some of System.Int32
There are many interesting uses for this information - for example, you could generate DB schema from F# unions or to create functions that will parse XML into a discriminated union (that describes the structure). I talked about the XML processing sample at GOTO conference earlier this year.