As you've stated this is just for a quick visual check, I would just divide by pi:
n = 0.7854;
disp(['n in terms of pi: ', num2str(n/pi), '*pi']);
>> n in terms of pi: 0.25*pi
If this was something you wanted to often do, I would define some function on your local path like so
function [val, str] = wrtpi(n)
% Returns the value of n with respect to pi
val = n/pi;
% Could include some rounding checks here if you wanted to complicate things
% ... *checks* ...
str = ['n in terms of pi: ', num2str(n/pi), '*pi'];
end
Then
n = 0.7854;
[val, str] = wrtpi(n)
>> val = 0.25
str = n in terms of pi: 0.25*pi
You also say this is just for identifying radian quadrants, aside from learning them, you could also just have a simple function
function q = quadrant(n)
Qs = pi*[0, 1/2, 1, 3/2]; % Quadrants
q = find(Qs <= mod(n,2*pi), 1, 'last'); % Index within the quadrants
% You could make this accept vector inputs using:
% q = arrayfun(@(x) find(Qs <= mod(x,2*pi), 1, 'last'), n)
end
Then
quadrant(2*pi - 0.0001) % >> 4
quadrant(0.2) % >> 1
quadrant(1.6) % >> 2
Note that using the symbolic math toolbox for something as simple as this will likely cause more complications and slowdown than it helps!