As pointed out by @Callum, Regex101 does not support C#. If you try it in C#, it does work:
[Test]
public void TestMatch()
{
// Arrange.
const string example = "123 écumé 456";
Regex pattern = new Regex(@"\bécumé\b");
// Act.
Match match = pattern.Match(example);
// Assert.
Assert.That(match.Success, Is.True);
}
Also to point out that when you say
the following does not find a match: "/\bécumé\b/iu"
The "/iu" in the string is not doing what you might think: in C# you can give regex options using a different parameter, not as part of the pattern string. For example:
Regex pattern = new Regex(@"\bécumé\b", RegexOptions.IgnoreCase);