+-----+--------------+--------+-----------+
| id | a_no | status | req_date |
+-----+--------------+--------+-----------+
| 1 | 6019-6039120 | 0 |2015-03-01 |
| 2 | 6019-6039120 | 0 |2015-03-01 |
| 4 | 6019-6039120 | 0 |2015-03-02 |
| 5 | 6019-6039121 | 0 |2015-03-02 |
| 6 | 6019-6039134 | 0 |2015-03-02 |
| 7 | 6019-6039134 | 0 |2015-03-02 |
| 8 | 6019-6039120 | 0 |2015-03-03 |
| 9 | 6019-6039129 | 0 |2015-03-03 |
| 10 | 6019-6039145 | 0 |2015-03-04 |
| 11 | 6019-6039167 | 0 |2015-03-04 |
+-----+--------------+--------+-----------+
This is my table structure, as you can see id=1 and id=2
have a same data. How to prevent the same data to insert into my table?