There cannot be a WHERE
clause in an INSERT ... VALUES ...
statement.
The normal pattern for avoiding duplicates is to add UNIQUE constraint(s).
If you want to avoid adding any duplicate "member_id" values, and you also want to avoid adding any duplicate "email" values, then
CREATE UNIQUE INDEX mytab_UX1 ON mytab (member_id);
CREATE UNIQUE INDEX mytab_UX2 ON mytab (email);
Whenever an INSERT or UPDATE attempts to create a duplicate value, a duplicate key exception (error) will be thrown. MySQL provides the IGNORE keyword which will suppress the error, and allow the statement to complete successfully, but without introducing any duplicates.
Given an empty table, the first statement would insert a row, the second and third statements would not.
INSERT IGNORE INTO mytab (member_id, email) VALUES (1,'k@live.com');
INSERT IGNORE INTO mytab (member_id, email) VALUES (2,'k@live.com');
INSERT IGNORE INTO mytab (member_id, email) VALUES (1,'aaa@bbb.com');
If you want to restrict just the combination of the two columns to being unique, that is you would allow the 2nd and 3rd statements to insert a row, then you'd add a UNIQUE constraint on the combination of the two columns, rather than two separate unique indexes as above.
CREATE UNIQUE INDEX mytab_UX1 on mytab (member_id, email);
Aside from that convention, say you don't have a unique constraint, but you only want to modify the behavior of the single insert statement, then you can use a SELECT statement to return the values you want to insert, and then you can add a WHERE clause to the SELECT.
To avoid adding any duplicate member_id or duplicate email, then something like this would accomplish that:
INSERT INTO mytab (member_id, email)
SELECT s.member_id, s.email
FROM (SELECT 1 AS member_id, 'k@live.com' AS email) s
WHERE NOT EXISTS (SELECT 1 FROM mytab d WHERE d.member_id = s.member_id)
AND NOT EXISTS (SELECT 1 FROM mytab e WHERE e.email = s.email)
For best performance with a large table, you're going to want at least two indexes, one with a leading column of member_id, and one with a leading column of email. The NOT EXISTS subqueries can make use of an index to quickly locate a "matching" row, rather than scanning every row in the table.)
Again, if it's just the combination of the two columns you want to be unique, you'd use a single NOT EXISTS subquery, as in your original query.
Alternatively, you could use an anti-join pattern as an equivalent to the NOT EXISTS subquery.
INSERT INTO mytab (member_id, email)
SELECT s.member_id, s.email
FROM (SELECT 2 AS member_id, 'k@live.com' AS email) s
LEFT
JOIN mytab d
ON d.member_id = s.member_id
LEFT
JOIN mytab e
ON e.email = s.email
WHERE d.member_id IS NULL
AND e.email IS NULL