Fat hydrogenation

Fat hydrogenation is the process of combining fat – typically liquid vegetable oils – with hydrogen, to convert some or all of the unsaturated fat into saturated fat, resulting in a solid or semi-solid fat.

Products with partially hydrogenated fat

Changing the degree of saturation of the fat changes some important physical properties, such as the melting range, which is why liquid oils become semi-solid. Solid or semi-solid fats are preferred for baking because the way the fat mixes with flour produces a more desirable texture in the baked product. Because partially hydrogenated vegetable oils are cheaper than animal fats, are available in a wide range of consistencies, and have other desirable characteristics such as increased oxidative stability and longer shelf life, they are the predominant fats used as shortening in most commercial baked goods.

The process is typically carried out at very high pressure, with the help of a nickel catalyst that is removed from the final product.

Process

Hydrogenating vegetable oil is done by raising a blend of vegetable oil and a metal catalyst, typically nickel, in near-vacuum to very high temperatures, and introducing hydrogen. This causes the carbon atoms of the oil to break double-bonds with other carbons. Each carbon atom becomes single-bonded to an individual hydrogen atom, and the double bond between carbons can no longer exist.

The desirable (left) and undesirable pathways for partial hydrogenation of an unsaturated fat.

Full hydrogenation results in the conversion of all of the unsaturated fats into saturated fats by transforming all of the double bonds in the fat into single bonds.[1] Partial hydrogenation reduces some, but not all, of the double bonds by the partial replacement with single bonds. The degree of hydrogenation is controlled by restricting the amount of hydrogen, reaction temperature and time, and the catalyst.[2]

Issues

Cistrans isomerization of some of the remaining unsaturated carbon bonds to their trans isomers during the hydrogenation process produces trans fat, which have been demonstrated to have cardiovascular health risk.[1][3] The conversion from cis to trans bonds is chemically favored because the trans configuration has lower energy than the natural cis one. At equilibrium, the trans/cis isomer ratio is about 2:1.

Numerous studies have concluded that these trans fatty acids have negative health effects. As a result, many countries have enacted trans fat regulation that aims to eliminate or severely restrict their amount in industrialized food products, such as mandatory labeling of trans fats on food products.[4][5] The United States Food and Drug Administration has concluded that partially hydrogenated oils are not generally recognized as safe, and since 2018 categorizes them as food additives, not food.[6]

Dietary recommendations

Many health organizations recommend limiting or replacing dietary intake of trans fats and saturated fats, in favor of unsaturated fats: [7]

History

Wilhelm Normann patented the hydrogenation of liquid oils in 1902

Nobel laureate Paul Sabatier worked in the late 1890s to develop the chemistry of hydrogenation.[8] Whereas Sabatier considered hydrogenation of only vapors, the German chemist Wilhelm Normann showed in 1901 that liquid oils could be hydrogenated, and patented the process in 1902.[9][10][11] Normann's hydrogenation process made it possible to stabilize affordable whale oil or fish oil for human consumption, a practice kept secret to avoid consumer distaste.[12] During the years 1905–1910, Normann built a fat-hardening facility in the Herford company. At the same time, the invention was extended to a large-scale plant in Warrington, England, at Joseph Crosfield & Sons, Limited. It took only two years until the hardened fat could be successfully produced in the plant in Warrington, commencing production in late 1909. The initial year's production totalled nearly 3,000 tonnes.[12]

Cover of original Crisco cookbook, 1912

In 1909, Procter & Gamble acquired the United States rights to the Normann patent.[13] In 1911, they began marketing the first hydrogenated shortening, Crisco, composed largely of partially hydrogenated cottonseed oil. Further success came from the marketing technique of giving away free cookbooks in which every recipe called for Crisco.

In the early 20th century, soybeans began to be imported into the United States as a source of protein; large quantities of soybean oil were a by-product. At the same time, there was not enough butterfat available for consumers. Margarine manufacturers found that hydrogenated fats worked better than the previously used combination of animal and liquid vegetable fats. Margarine made from hydrogenated soybean oil and vegetable shortenings such as Crisco and Spry, sold in England, began to replace butter and lard in baking bread, pies, cookies, and cakes by 1920.[14]

Production of hydrogenated fats increased steadily until the 1960s, as processed vegetable fats replaced animal fats in the United States and other Western countries. At first, the argument was a financial one due to lower costs; advocates also said that the hydrogenated fats of margarine were healthier than the saturated fats of butter.[15]

The food industry has moved away from partially hydrogenated fats in response to the health concerns about trans fats, labeling requirements, and removal of trans fats from permitted food additives.[16][17][18] They have been replaced with fully hydrogenated fats, vegetable oils that are naturally higher in saturated fat and therefore more solid at room temperature, such as palm oil and coconut oil, and interesterified fats, which cannot result in the formation of trans fats.

See also

  • Hydrotreated vegetable oil

References

  1. "Hydrogenation - an overview | ScienceDirect Topics". www.sciencedirect.com.
  2. Ian P. Freeman "Margarines and Shortenings" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. doi:10.1002/14356007.a16_145
  3. Teresa Tarrago-Trani, Maria; Phillips, Katherine M.; Lemar, Linda E.; Holden, Joanne M. (2006). "New and Existing Oils and Fats Used in Products with Reduced Trans-Fatty Acid Content" (PDF). Journal of the American Dietetic Association. 106 (6): 867–880. doi:10.1016/j.jada.2006.03.010. PMID 16720128.
  4. "Deadly fats: why are we still eating them?". The Independent. 2008-06-10. Archived from the original on 2008-06-14. Retrieved 2008-06-16.
  5. "New York City passes trans fat ban". NBC News. 2006-12-05. Retrieved 2010-01-09.
  6. "F.D.A. Gives Food Industry 3 Years to Eliminate Trans Fats". The New York Times. 2015-06-16. Archived from the original on 2015-06-16. Retrieved 2015-06-16.
  7. the American Heart Association,Sacks FM, Lichtenstein AH, Wu JH, Appel LJ, Creager MA, Kris-Etherton PM, Miller M, Rimm EB, Rudel LL, Robinson JG, Stone NJ, Van Horn LV (July 2017). "Dietary Fats and Cardiovascular Disease: A Presidential Advisory From the American Heart Association". Circulation. 136 (3): e1–e23. doi:10.1161/CIR.0000000000000510. PMID 28620111. S2CID 367602.the World Health Organization, Health Canada,"Choosing foods with healthy fats". Health Canada. 2018-10-10. Retrieved 2019-09-24., the US Department of Health and Human Services,"Cut Down on Saturated Fats" (PDF). United States Department of Health and Human Services. Retrieved 2019-09-24. the UK National Health Service,"Fat: the facts". United Kingdom's National Health Service. 2018-04-27. Retrieved 2019-09-24. the UK Scientific Advisory Committee on Nutrition"Saturated Fats and Health". Scientific Advisory Committee on Nutrition (SACN). Retrieved 26 July 2021], the Australian Department of Health and Aging,"Fat". Australia's National Health and Medical Research Council and Department of Health and Ageing. 2012-09-24. Retrieved 2019-09-24. the Singapore Ministry of Health,"Getting the Fats Right!". Singapore's Ministry of Health. Retrieved 2019-09-24. the Indian Ministry of Health and Family Welfare,"Health Diet". India's Ministry of Health and Family Welfare. Retrieved 2019-09-24. the New Zealand Ministry of Health,"Making healthier food choices". New Zealand's Ministry of Health. Retrieved 2021-06-03. and Hong Kong's Department of Health."Know More about Fat". Hong Kong's Department of Health. Retrieved 2019-09-24.
  8. Nobel Lectures, Chemistry, 1901–1921. Elsevier. 1966. Reprinted online: "Paul Sabatier, The Nobel Prize in Chemistry 1912". Nobel Foundation. Retrieved 7 January 2007.
  9. de 141029 Process for converting unsaturated fatty acids or their glycerides into saturated compounds
  10. gb 190301515 Process for converting unsaturated fatty acids or their glycerides into saturated compounds
  11. Patterson HB (1998). "Hydrogenation" (PDF). Sci Lecture Papers Series. Archived from the original (PDF) on 26 September 2007. Retrieved 7 January 2007.
  12. "Wilhelm Normann und die Geschichte der Fetthärtung von Martin Fiedler, 2001". 20 December 2011. Archived from the original on 1 October 2011. Retrieved 14 August 2007.
  13. Shurtleff W, Aoyagi A. "History of Soybeans and Soyfoods: 1100 B.C. to the 1980s". Archived from the original on 18 October 2005.
  14. Kummerow FA (2008). Cholesterol Won't Kill You – But Trans Fat Could. Trafford Publishing. ISBN 978-1-4251-3808-0. NOTE: Unreliable source.
  15. Ascherio A, Stampfer MJ, Willett WC (1999). "Trans fatty acids and coronary heart disease". The New England Journal of Medicine. 340 (25): 1994–8. doi:10.1056/NEJM199906243402511. PMID 10379026. Archived from the original on 3 September 2006. Retrieved 14 September 2006.
  16. "Ask the Experts: Hydrogenated Oils". Berkeley Wellness. Remedy Health Media. October 1, 2011. Retrieved 24 November 2018.
  17. Collette, Robert L. (July 7, 2015). "Why a Monograph for Fully Hydrogenated Oils and Fats is Needed". Quality Matters. United States Pharmacopeial Convention. Retrieved 24 November 2018.
  18. Haynes, Fiona (September 23, 2018). "Partially vs. Fully Hydrogenated Oils: The Truth About Trans Fats". The Spruce Eats. Dotdash. Retrieved 24 November 2018.
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