Debye

The debye (symbol: D) (/dɛˈb/;[1] Dutch: [dəˈbɛiə]) is a CGS unit[2] (a non-SI metric unit) of electric dipole moment[note 1] named in honour of the physicist Peter J. W. Debye. It is defined as 10−18 statcoulomb-centimeters.[note 2] Historically the debye was defined as the dipole moment resulting from two charges of opposite sign but an equal magnitude of 10−10 statcoulomb[note 3] (generally called e.s.u. (electrostatic unit) in older scientific literature), which were separated by 1 ångström.[note 4] This gave a convenient unit for molecular dipole moments.

1 D = 10−18 statC·cm
= 10−18 cm5/2⋅g1/2⋅s−1 [note 5]
= 10−10 statC·Å [note 2]
1/299792458×1021 C·m[note 6]
3.33564×10−30 C·m
0.3934303 e·a0 [note 7]
0.2081943 e⋅Å
0.02081943 e·nm

Typical dipole moments for simple diatomic molecules are in the range of 0 to 11 D. Symmetric homoatomic species, e.g. chlorine, Cl2, have zero dipole moment, and highly ionic molecular species have a very large dipole moment, e.g. gas-phase potassium bromide, KBr, with a dipole moment of 10.41 D.[3] A proton and an electron 1Å apart have a dipole moment of 4.8 D.

The debye is still used in atomic physics and chemistry because SI units have until recently been inconveniently large. The smallest SI unit of electric dipole moment is the quectocoulomb-metre, which corresponds to roughly 0.3 D.[note 8]

See also

  • Buckingham (unit) (CGS unit of electric quadrupole)

Notes

  1. Two equal and opposite charges separated by some distance constitute an electric dipole. This dipole possesses an electric dipole moment whose value is given as charge times length of separation, it is a vector whose direction is in the direction of the unit vector of the position vector of the positive charge w.r.t negative charge:
    p = qr.
  2. The statcoulomb is also known as the franklin or electrostatic unit of charge.
    1 statC = 1 Fr = 1 esu = 1 cm3/2⋅g1/2⋅s−1.
  3. 10−10 statcoulomb corresponds to approximately 0.2083 units of elementary charge.
  4. The ångström is within an order of magnitude of the nuclear separation for a typical covalent bond.
    1 Å = 100 pm = 10−8 cm = 10−10 m.
  5. In any of the CGS systems, electromagnetic units are expressed in terms of the three base units, cm, g and s, albeit the systems are mutually inconsistent in this regard.
  6. One debye corresponds to 1×10−21 C·m2/s divided by the numeric value of the speed expressed in m/s. Conversely, 1 C·m ≘ 2.9979×1029 D.
  7. The product e·a0 is also called the atomic unit of electric dipole moment (see Atomic unit of electric dipole moment, NIST.)
  8. With a value of 10−30, quecto- is the smallest SI prefix, accepted as an SI prefix by the CGPM on 18 November 2022.

References

  1. "Debye". Random House Dictionary. 2013.
  2. CGS units Archived 2011-08-09 at the Wayback Machine R. Rowlett (University of North Carolina at Chapel Hill).
  3. Physical chemistry 2nd Edition (1966) G. M. Barrow. McGraw-Hill.
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